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This phrase means that someone is being prim and proper with a cool kind of demeanour. But from what event or phenomenon or occurrence was this idiom derived from, and when?

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    Never having known the history, I had always thought it meant not proper but just plain cold, rigid, and emotionally negative, and that it was just a clever turn of phrase created to imply 'cold'.
    – Mitch
    Commented May 14, 2011 at 16:52

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The Phrase Finder has a citation from 1530, in Jehan Palsgrave's Lesclarcissement de la langue françoyse:

He maketh as thoughe butter wolde nat melte in his mouthe.

It goes on to say,

The phrase is usually used in a derogatory and critical sense and, in the past at least, was most often applied to women. Occasionally, it was used to denote a quiet meekness and sweetness of temper rather than emotional coldness. For example, this description of Mr Pecksniff in Charles Dickens' Martin Chuzzlewit:

It would be no description of Mr Pecksniff's gentleness of manner to adopt the common parlance, and say that he looked at this moment as if butter wouldn't melt in his mouth. He rather looked as if any quantity of butter might have been made out of him, by churning the milk of human kindness, as it spouted upwards from his heart.

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    Since your whole answer is a direct quote from The Phrase Finder, you should make it more clear that these are not your words. Commented May 14, 2011 at 13:58
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    More clear? Hey users, these are not my words, these are not my words;)
    – user8568
    Commented May 14, 2011 at 16:17
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    This is terrible formatting the way it stands right now. You need to clearly show that what is not blockquoted -- the "this is an old phrase" and "the phrase is usually used in a derogatory sense" -- are not your words. I'm not sure I like the fact that the entire post is cribbed almost verbatim from the Phrase Finder; there's nary an original thought of yours to be found as commentary.
    – Uticensis
    Commented May 21, 2011 at 10:32
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Eric Partridge offers this citation in A Dictionary of Slang and Unconventional English:

butter would not melt in one's mouth, (look) as if (To seem) demure. Coll. from the 1530's; Palsgrave (O.E.D.), Latimer, Sedley, Swift, Scott, Thackeray. In reference to women, Swift and Grose add: yet, I warrant you, cheese would not choke her, the meaning of which must be left to the reader who will look at cheese.

So, onward to cheese, we find — nothing useful. Partridge is curiously silent on the subject, at least as it relates to this case directly. I wonder if his reticence might be due to one unsavory meaning of the word, use of cheese for smegma, giving the whole thing a lewd sexual connotation. But I can find nothing in the O.E.D. or elsewhere to support this contention. Still, if cheese is somehow related to butter in this context, this could well shed a whole new light on that phrase as well. But given the lack of sources, I have to conclude this is a dead end.

Still, we might also consider another meaning of butter as "fulsome flattery, unctuous praise" (Partridge). A young woman who was demure, as Partridge calls it, would be likely to receive much of this kind of butter.

demure |diˈmyoŏr| adjective ( -murer, -murest) (of a woman or her behavior) reserved, modest, and shy : a demure little wife who sits at home minding the house.

A woman who was "reserved, modest, and shy" would probably seem a little cold, and certainly resistant to the kind of buttering flattery that might come her way.

Upon further review, more than a decade later

Regarding the "yet, I warrant you, cheese would not choke her" in the context of "butter would not melt in her mouth," as a kind of rebuttal to that thought, perhaps although the woman in question seemed cool on the outside, perhaps it is by way of suggesting that she is passionate on the inside, hot enough to melt said cheese. Just a thought.

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I would offer the suggestion that butter and cheese though both dairy products have varying melting points. Though butter may go soft at room temperature (and some cheeses) I might infer that the suggestion from this quote may be that cheese would in fact melt in her mouth and therefore butter wouldn't stand a chance. The key to this being that she 'looks' as though butter wouldn't melt although the truth is that cheese would not choke her. Perhaps therefore it has 'melted' or at least gone soft. Good old hot lips.

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