Every technical writing style guide that I have seen that addresses the issue says to leave no space between numerals and mathematical symbols used as modifiers or adjectives. A few examples include:
Use a space “Before but not after + - ± ... when used as adjectives.” (Mathematics into Type: Updated Edition, 1999, American Mathematical Society, p. 39, §3.1.3c.)
“When mathematical symbols are used as adjectives, that is, with one number that is not part of a mathematical operation, do not leave a space between the symbol and the number.” (The ACS Style Guide, 3d ed, 2006, American Chemical Society, p. 215) [The listed examples include ±, >, <, and %.]
“Leave no space after mathematical operators used as adjectives” (The ACS Style Guide, 3d ed, 2006, American Chemical Society, p. 219)
“Generally, close up a number and a non alphabetic [math] symbol, whether the symbol precedes or follows the number (except if the symbol is being used as a mathematical operator).” (Scientific Style and Format, 7th ed, 2006, Cambridge University Press, p. 146)
“When these [mathematical] symbols are modifying a number rather than serving as operators, close them up to the numeral that follows or write them out.” (Scientific Style and Format, 7th ed, 2006, Cambridge University Press, p. 159)
“The signs +, -, ±, ×, and ÷, etc., are closed against accompanying figures and symbols.” (U.S. Government Printing Office Style Manual, 2008, p. 259, Rule 10.2)