When did a ‘silk hat’ become a Top Hat?
I found no evidence that the name top hat existed prior 1875. Even the British Chambers' Encyclopaedia: A Dictionary of Universal Knowledge for the People, printed in 1874, didn't mention top hat in its “hat” entry but spoke extensively about beaver and silk hats.
Numerous websites and books cite the Hatter's Gazette article about an Englishman named John Hetherington, who in 1797 was arrested for wearing a “silk hat”. Apparently, its shocking appearance was responsible for inciting a riot; women fainted, children screamed, and dogs barked wildly. He was later fined — an astronomical sum in those days — £500. Despite the reams of citations online and off, there are no surviving records of the Hatter's Gazette article.
A special thank you goes to @Josh61 who found the earliest online excerpts of top hat dated 1875
In The Ladies' Gallery. By Madame Ch. Hundreds
the rule is to wear your hat in the House, [the house of Commons] and a very odd effect it has to see men sitting about in a well-lighted and warm chamber with their hats on their heads. [...] Mr. John Martin. ... it appears, had never, before County Meath sent him to Parliament, worn a hat of the hideous shape which fashion entails upon our suffering male kindred. [...] “Never,” Mr. Martin is reported to have said ... “never will I stoop to wear a top hat. I never had one on my head, and the Saxon shall never make me put it there.” He was as good as his word when he first came to town, and was wont to appear in a low- crowned beaver hat of uncertain architecture. But after he had, for some weeks, assisted the process of Legislature under the shadow of this hat, the Speaker privately and in considerate terms conveyed to him a hint that, in the matter of hats at least, it was desirable to have uniformity in the House of Commons.
Mr. Martin, [...] abandoned the nondescript hat and sacrificed his inclinations and principles to the extent of buying what he calls “a top hat.” But he has not taken kindly to it, and never will.
The next excerpt tells us that, surprisingly, top hat in the 1870s was slang, its original name was beaver.
The Gentleman Cadet
I was in the rear of the division, and dressed in plain clothes; my hat was what modern slang would term “a top hat,” and what in those days we called “a beaver.” This beaver I was rather proud of; it was only the second one I had possessed, a cap having previously done duty for the covering of my head
The true inventor of the silk hat, which later became known as top hat, was always an Englishman.
The Chronicle of Hats in Enjoyable Quotes By Ida Tomshinsky
The first official recorded history of what we now refer to a silk top hat made from silk plush in England is always credited to George Dunnage, a hatter from Middlesex in 1793
[...] Dunnage's silk hat was initially described as “imitation of beaver.”
Why “top”?
Top hats between the years 1840 and 1850 became incredibly tall, some reaching eight inches in height. This would explain why the silk hat was also known as “chimney-pot hat”, “stove pipe hat”, “high hat”, “high silk hat” and “cylinder hat” (Wikipedia)
Barrie England's supposition, “it was a hat that had a top”, could explain how the hat earned its slang term, the distinctive headgear certainly had a flat top. Note the word top is set off with quotation marks in the excerpt below.
Collapsible top-hats

On May 5, 1812, a London hatter called Thomas Francis Dollman patented a design for "an elastic round hat" supported by ribs and springs. His patent was described as:
An elastic round hat, which "may be made of beaver, silk, or other materials." "The top" of the crown and about half an inch from the top "as well as "the brim and about an inch , the crown from the bottom" are stiffened in the ordinary manner. […]
Below, a typical 1800s beaver hat
source

Brighton ‘Toppers’
This has to be one of the oddest photos that cropped up while I was hunting down the beaver / silk hat / top hat. The group of topless men belong to Brighton's Swimming Club, the oldest swimming club in Great Britain. Some say the photo was taken as far back as 1863, while others sustain the 1900s is a more realistic date. Nevertheless, it does show the incredible difference in height and styles these “toppers” were made in.
