Desperacy is “not a word”1 because just plain despair alone plenty suffices as a noun, without any redundantly tedious nominalizationalizing suffixes and postfixes and add-on-the-enders.
The take-away lesson here is that sometimes, perhaps even often, it is far better to trim things off instead of tack them on.
That is, not a word attested2 by the Oxford English Dictionary.
That is, not a word attested as being current in contemporary English.
However, the OED does attest an obsolete word †ˈdesperacy,
and for which it provides no citation later than from the 18th century.
As for the second part of your question, here are some attested triples that may interest you:
- adequacy, adequate, adequation
- advocacy, advocate, advocation
- alternacy, alternate, alternation
- articulacy, articulate, articulation
- automacy, automate, automation
- complicacy, complicate, complication
- confederacy, confederate, confederation
- conjugacy, conjugate, conjugation
- degeneracy, degenerate, degeneration
- delegacy, delegate, delegation
- determinacy, determinate, determination
- effeminacy, effeminate, effemination
- episcopacy, episcopate, episcopation
- illegitimacy, illegitimate, illegitimation
- inadequacy, inadequate, inadequation
- inarticulacy, inarticulate, inarticulation
- inchoacy, inchoate, inchoation
- indeterminacy, indeterminate, indetermination
- inebriacy, inebriate, inebriation
- inordinacy, inordinate, inordination
- intermediacy, intermediate, intermediation
- intestacy, intestate, intestation
- intimacy, intimate, intimation
- itineracy, itinerate, itineration
- legitimacy, legitimate, legitimation
- lunacy, lunate, lunation
- numeracy, numerate, numeration
- obduracy, obdurate, obduration
- oracy, orate, oration
- prelacy, prelate, prelation
- privacy, private, privation
- profligacy, profligate, profligation
- prolificacy, prolificate, prolification
- regeneracy, regenerate, regeneration
- reprobacy, reprobate, reprobation
- subordinacy, subordinate, subordination
- surrogacy, surrogate, surrogation
- testacy, testate, testation
- ultimacy, ultimate, ultimation
- unregeneracy, unregenerate, unregeneration