The reason why a pair of is used for an item of clothing worn on legs is partly related to the history of clothing and tailoring. For example, pants (short of pantaloons, U.S. English) or trousers became a single garment late in the history. Before modern tailoring, such garments were made in two pieces, two seperateseparate sleeves of fabric called a hose which were tied to a belt with braces and the open crotch was covered with breeches. The plural usage of these garments persisted out of habit even after they had started being made in one piece in modern tailoring. A shirt and similar upper-body garments were always a single piece of clothing, so they were singular.