In general
X is deceptively Y
can be interpreted as
X has a greater quality of Y than you might at first assume or observe
Now, with regard to
He looks deceptively strong
Someone with experience of this deceptiveness, let's say for example a pro-wrestler, might observe some other wrestler, a thin one, and conclude, based on their experience, that the skinny appearance belies a strength or compensating quality that should not be dismissed or underestimated in the ring. To this pro-wrestler the skinny person appears strong, precisely because to the average non-wrestler they would appear weak.
To the observing wrestler, the skinny wrestler appears both strong (to her) and deceptive (to others), hence looking deceptively strong.