After searching around and reading a bit, the only place I saw someone actually use a term for it was here, where it is referred to as odd pricing.
Odd-even Pricing. Most supermarkets tend to use the so-called “odd” prices—those ending in .99 or .95—rather than round dollar figures. Many believe that this practice is intended to make prices seem lower than they are. For example, $2.99 could be seen as “two dollars plus ‘change’” rather than “almost three dollars.” Research shows that consumers are slightly more likely to purchase at these odd prices, but the effect is not large. Odd prices may send a signal that a product is a “bargain.”...